Relationships between microstructural and mechanical aging effects in eutectic PbSn and Pb-free solder alloy Sn3.9Ag0.6Cu are reported and compared. The room temperature aged Sn3.9Ag0.6Cu alloy continually age-softened, this softening correlated with the growth of relatively large tin-rich crystals. The aged Sn3.9Ag0.6Cu alloy initially age-softened, and the minimum flow strength was reached after one day at This softening correlated with the growth of relatively large tin-rich crystals and with the coarsening of particles. When aged at beyond one day the Sn3.9Ag0.6Cu alloy age-hardened, the hardening correlated with the dispersion of particles into tin-rich crystals which previously had not contained intermetallic precipitates.
Issue Section:
Technical Papers
Keywords:
tin alloys,
silver alloys,
copper alloys,
eutectic alloys,
ageing,
crystal microstructure,
softening,
dispersion hardening,
tensile testing,
quench hardening,
solders
Topics:
Alloys,
Solders,
Temperature,
Eutectic alloys,
Lead-free solders,
Tin,
Hardening,
Tensile strength
1.
Anderson
, I. E.
, Foley
, J. C.
, Cook
, B. A.
, Harringa
, J.
, Terpstra
, R. L.
, and Unal
, D.
, 2001
, “Alloying Effects in Near-Eutectic Sn-Ag-Cu Solder Alloys for Improved Microstructural Stability
,” ASME J. Electron. Mater.
, 30
(9
), pp. 1050
–1059
.2.
Lin
, K. L.
, Hsiao
, C. C.
, and Chen
, K. I.
, 2002
, “Microstructural Evolution of Sn-Ag-Cu-Al Solder with Respect to Al Content and Heat Treatment
,” J. Mater. Res.
, 17
(9
), pp. 2386
–2393
.3.
Ye
, L.
, Lai
, Z. H.
, Liu
, J.
, and Tholen
, A.
, 2001
, “Microstructure Investigation of Sn-0.5Cu-3.5Ag and Sn-3.5Ag-0.5Cu-0.5B Lead-free Solders
,” Soldering & Surface Mount Technology
, 13
(3
), pp. 16
–20
.4.
Miyazawa
, Y.
, and Ariga
, T.
, 2001
, “Influence of Aging Treatment on Microstructure and Hardness of Sn-(Ag, Bi, Zn) Eutectic Solder Alloys
,” Mater. Trans., JIM
, 42
(5
), pp. 776
–782
.5.
Lee
, T. Y.
, Choi
, W. J.
, Tu
, K. N.
, Jang
, J. W.
, Kuo
, S. M.
, Lin
, J. K.
, Frear
, D. R.
, Zeng
, K.
, and Kivilahti
, J. K.
, 2002
, “Morphology, Kinetics, and Thermodynamics of Solid-State Aging of Eutectic PbSn and Pb-free Solders(Sn-3.5Ag, Sn-3.8Ag-0.7Cu and Sn-0.7Cu) on Cu
,” J. Mater. Res.
, 17
(2
), pp. 291
–301
.6.
Vianco
, P. T.
, and Rejent
, J. A.
, 2002
, “A Methodology to Establish Baseline Metrics for Assessing the Isothermally Aging of Sn-Pb Solder Interconnects
,” Soldering and Surface Mount Technology
, 14
(2
), pp. 26
–34
.7.
Grusd, A., 1997, Lead Free Solders in Electronics, SMI, pp. 648–661.
8.
Zeng
, K.
, and Tu
, K. N.
, 2002
, “Six Cases of Reliability Study of Lead-Free Solder Joints in Electronic Packaging Technology
,” Mater. Sci. Eng., R.
, 38
, pp. 55
–105
.9.
Oh
, C.
, Shim
, S. J. H.
, Lee
, B. J.
, and Lee
, D. N.
, 1996
, “A Thermodynamic Study on the Ag-Sb-Sn System
,” J. Alloys Compd.
, 238
, pp. 155
–166
.10.
Hayes
, F. H.
, Lukas
, H. L.
, Effenberg
, G.
, and Petzow
, G.
, 1986
, “The Thermodynamic Optimization of the Cu-Ag-Pb System
,” Z. Metallkde
, 77
, pp. 749
–754
.Copyright © 2004
by ASME
You do not currently have access to this content.