Relationships between microstructural and mechanical aging effects in eutectic PbSn and Pb-free solder alloy Sn3.9Ag0.6Cu are reported and compared. The room temperature aged Sn3.9Ag0.6Cu alloy continually age-softened, this softening correlated with the growth of relatively large tin-rich crystals. The 180°C aged Sn3.9Ag0.6Cu alloy initially age-softened, and the minimum flow strength was reached after one day at 180°C. This softening correlated with the growth of relatively large tin-rich crystals and with the coarsening of Ag3Sn particles. When aged at 180°C beyond one day the Sn3.9Ag0.6Cu alloy age-hardened, the hardening correlated with the dispersion of Ag3Sn particles into tin-rich crystals which previously had not contained intermetallic precipitates.

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