Ultraslow diffusion is characterized by a logarithmic growth of the mean squared displacement (MSD) as a function of time. It occurs in complex arrangements of molecules, microbes, and many-body systems. This paper reviews mechanical models for ultraslow diffusion in heterogeneous media from both macroscopic and microscopic perspectives. Macroscopic models are typically formulated in terms of a diffusion equation that employs noninteger order derivatives (distributed order, structural, and comb models (CM)) or employs a diffusion coefficient that is a function of space or time. Microscopic models are usually based on the continuous time random walk (CTRW) theory, but use a weighted logarithmic function as the limiting formula of the waiting time density. The similarities and differences between these models are analyzed and compared with each other. The corresponding MSD in each case is tabulated and discussed from the perspectives of the underlying assumptions and of real-world applications in heterogeneous materials. It is noted that the CMs can be considered as a type of two-dimensional distributed order fractional derivative model (DFDM), and that the structural derivative models (SDMs) generalize the DFDMs. The heterogeneous diffusion process model (HDPM) with time-dependent diffusivity can be rewritten to a local structural derivative diffusion model mathematically. The ergodic properties, aging effect, and velocity autocorrelation for the ultraslow diffusion models are also briefly discussed.
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July 2019
Review Articles
A Survey of Models of Ultraslow Diffusion in Heterogeneous Materials
Yingjie Liang,
Yingjie Liang
Institute of Soft Matter Mechanics,
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China;
State Key Laboratory of Geohazard Prevention
and Geoenvironment Protection,
Chengdu University of Technology,
Chengdu 610059, Sichuan, China
e-mail: liangyj@hhu.edu.cn
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China;
State Key Laboratory of Geohazard Prevention
and Geoenvironment Protection,
Chengdu University of Technology,
Chengdu 610059, Sichuan, China
e-mail: liangyj@hhu.edu.cn
1Corresponding authors.
Search for other works by this author on:
Shuhong Wang,
Shuhong Wang
Institute of Soft Matter Mechanics,
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
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Wen Chen,
Wen Chen
Institute of Soft Matter Mechanics,
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
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Zhifang Zhou,
Zhifang Zhou
College of Earth Science and Engineering,
Hohai University,
Nanjing 211100, Jiangsu, China
Hohai University,
Nanjing 211100, Jiangsu, China
Search for other works by this author on:
Richard L. Magin
Richard L. Magin
Richard and Loan Hill Department of
Bioengineering,
University of Illinois at Chicago,
Chicago, IL 60607
e-mail: rmagin@uic.edu
Bioengineering,
University of Illinois at Chicago,
Chicago, IL 60607
e-mail: rmagin@uic.edu
1Corresponding authors.
Search for other works by this author on:
Yingjie Liang
Institute of Soft Matter Mechanics,
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China;
State Key Laboratory of Geohazard Prevention
and Geoenvironment Protection,
Chengdu University of Technology,
Chengdu 610059, Sichuan, China
e-mail: liangyj@hhu.edu.cn
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China;
State Key Laboratory of Geohazard Prevention
and Geoenvironment Protection,
Chengdu University of Technology,
Chengdu 610059, Sichuan, China
e-mail: liangyj@hhu.edu.cn
Shuhong Wang
Institute of Soft Matter Mechanics,
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
Wen Chen
Institute of Soft Matter Mechanics,
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
College of Mechanics and Materials,
Hohai University,
Nanjing 211100, Jiangsu, China
Zhifang Zhou
College of Earth Science and Engineering,
Hohai University,
Nanjing 211100, Jiangsu, China
Hohai University,
Nanjing 211100, Jiangsu, China
Richard L. Magin
Richard and Loan Hill Department of
Bioengineering,
University of Illinois at Chicago,
Chicago, IL 60607
e-mail: rmagin@uic.edu
Bioengineering,
University of Illinois at Chicago,
Chicago, IL 60607
e-mail: rmagin@uic.edu
1Corresponding authors.
Manuscript received February 18, 2019; final manuscript received June 2, 2019; published online July 9, 2019. Assoc. Editor: Petia Vlahovska.
Appl. Mech. Rev. Jul 2019, 71(4): 040802 (16 pages)
Published Online: July 9, 2019
Article history
Received:
February 18, 2019
Revised:
June 2, 2019
Citation
Liang, Y., Wang, S., Chen, W., Zhou, Z., and Magin, R. L. (July 9, 2019). "A Survey of Models of Ultraslow Diffusion in Heterogeneous Materials." ASME. Appl. Mech. Rev. July 2019; 71(4): 040802. https://doi.org/10.1115/1.4044055
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